Enantio- and regioselective heck-type reaction of arylboronic acids with 2,3-dihydrofuran |
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| Authors: | Penn Liza Shpruhman Alina Gelman Dmitri |
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| Affiliation: | Department of Organic Chemistry, The Hebrew University of Jerusalem, Jerusalem, 91904 Israel. |
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| Abstract: | Reported herein is a protocol for the enantioselective Pd(II)-catalyzed Heck-type reaction between arylboronic acids and 2,3-dihydrofuran. The highest chemical and optical yields were obtained when a Pd(OAc)2/(R)-MeO(biphenylphosphine) or a Pd(OAc)2/(R)-(2,2'-bis(diphenylphosphino)-1,1'-binaphthyl) catalyst and a Cu(OAc)2 reoxidant were employed. |
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