(2+2)RESONANCE-ENHANCED MULTIPHOTON IONIZATION-FRAGMENTATION STUDY OF DIMETHYLAMINE |
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Affiliation: | Laser Spectroscopy Laboratory,Anhui Institute of Optics and Fine Mechanics,Academia Sinica,Heifei 230031, China |
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Abstract: | The multiphoton ionization spectra of dimethylamine are given in the 445-470 nm region. A time of flight mass spectrometer was used,and experiment was done under collision free condition. It is found that (2+2) resonance enhanced multiphoton ionization through (nN,3s) Rydberg state produces parent ions which endure pseudo-$alpha$ and C—N bond cleavages. The former forms CH3N+H=CH2 ions,and the latter gives CH2=N+H2 ions . |
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