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高聚物在超临界二氧化碳介质中的溶胀行为
引用本文:叶树集,陈鸣才,黄玉惠,丛广民.高聚物在超临界二氧化碳介质中的溶胀行为[J].广州化学,1999(2).
作者姓名:叶树集  陈鸣才  黄玉惠  丛广民
作者单位:中科院广州化学研究所!广州510650
摘    要:研究了LDPE、PP、PA6、EVA、PS、PU六种聚合物在超临界CO2 中的溶胀情况 ,观测了溶胀温度、溶胀压力、溶胀时间和降压时间对聚合物溶胀前后重量变化的影响以及溶胀后聚合物中CO2 的解吸曲线。

关 键 词:超临界CO_2  溶胀  溶胀温度  溶胀压力  溶胀时间  降压时间  解吸曲线

Swelling Behavior of Polymers in Supercritical Carbon Dioxide
Ye Shuji,Chen Mingcai,Huang Yuhui,Cong Guangmin.Swelling Behavior of Polymers in Supercritical Carbon Dioxide[J].Guangzhou Chemistry,1999(2).
Authors:Ye Shuji  Chen Mingcai  Huang Yuhui  Cong Guangmin
Abstract:A systematic study of supercritical carbon dioxide swelling six different polymers,namely,LDPE,PP,PA6,EVA,PS,PU,was investigated.When critical factors such as temperature,pressure and time of the SC-CO 2 treatment,and dimension of samples were changed,changes in appearance and weight had been observed.The weight change of polymers after treatment in mass with time showed a linear dependence on the logarithm of time.
Keywords:supercritical carbon dioxide  swelling  exposure temperature  exposure pressure  exposure time  decompression time  desorption curve    
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