| Abstract: | Acoustic anomalies of relaxor ferroelectric Na1/2Bi1/2TiO3 single crystals were investigated over a wide temperature range from ?196 °C to 900 °C by using Brillouin spectroscopy. The longitudinal sound velocity, the acoustic absorption coefficient and the elastic constant C11 were determined for the acoustic phonon mode propagating in the 100] direction. Two acoustic anomalies, weaker ones at the cubic-tetragonal phase transition temperature of ~540 °C and more pronounced ones at temperatures near 315 °C near the dielectric maximum temperature, were investigated and discussed in relation with the relevant order parameters coupled to the acoustic waves. The relaxation dynamics in the cubic phase were studied based on the flattening of the mode frequency and the half width, which was observed for the first time, and a modified Arrhenius law. |
