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Calorimetric study of liquid gadolinium-based alloys |
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| Authors: | Kanibolotsky D S Golovataya N V Lisnyak V V |
| Institution: | (1) Biophysical Department, Academician Peter Bogach Institute, Glushkova Ave. 2, corpus 12, 03022 Kyiv, Ukraine;(2) Chemical Department of, Kyiv National Taras Shevchenko University, Volodymyrska Str, 64, 01033 Kyiv, Ukraine |
| Abstract: | The enthalpies of mixing of liquid Gd-Si (1770±5 K) and Al-Gd (1760±5 K) alloys have been measured by high-temperature isoperibolic calorimetry. The calorimetric study of the gadolinium-based liquid alloys demonstrates the great negative enthalpies of mixing, which is associated with the contribution of GdSi and GdAl2 intermetallides into the liquid-state thermodynamics. The comparison of obtained results with literature data has been performed. This revised version was published online in August 2006 with corrections to the Cover Date. |
| Keywords: | mixing enthalpy gadolinium-silicon liquid alloys calorimetry aluminium-gadolinium |
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