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Solvent effects on the anation ofcis-diaquo-bis-ethylenediamine cobalt(III) by L-proline

Authors:

Debabrata Chatterjee Gauri Sankar De

Institution:

1. Department of Chemistry, University of Burdwan, 713104, Burdwan, India

Abstract:

The anation kinetics of the title complex were investigated spectrophotometrically in aqueous methanol, ethanol, ipropanol, t-butanol and dioxane, and the following rate law was established:

$dCo(en)_2 (P)^{2 + } ]/dt = \frac{{k_a K_E cis - Co(en)_2 (H_2 O)_2^{3 + } ]_T P.H]}}{{1 + K_E P.H]}}$

Keywords:
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