Transition metal sulfur dioxide hexafluoroarsenates and hexafluoroantimonates |
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| Authors: | E Lork R Mews J Petersen M Schrter B
emva |
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| Institution: | E. Lork, R. Mews, J. Petersen, M. Schröter,B. 
emva |
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| Abstract: | The preparation and characterization by X-ray crystallography of transition metal sulfur dioxide hexafluoroarsenates of the general formula M(SO2)x](AsF6)2 1 (1a: M=Mn, x=2; 1c: M=Co, x=4; 1e: M=Cu, x=4) and the hexafluoroantimonate Co(SO2)2](SbF6)2 3 is reported. The structural features of the compounds mentioned are compared with those of Fe(SO2)4](AsF6)2 (1b) and Ni(SO2)6](AsF6)2 (1d), reported previously. The structural diversity of transition metal sulfur dioxide complexes is discussed. |
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| Keywords: | Sulfur dioxide complexes Transition metal hexafluoroarsenates Hexafluoroantimonates X-ray structures |
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