A microporous lanthanide metal-organic framework containing channels:Synthesis,structure,gas adsorption and magnetic properties |
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Authors: | LI HuanHuan NIU Zheng HAN Tian ZHANG ZhenJie SHI Wei & CHENG Peng Key Laboratory of Advanced Energy Materials Chemistry Ministry of Education |
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Affiliation: | LI HuanHuan,NIU Zheng,HAN Tian,ZHANG ZhenJie,SHI Wei & CHENG Peng* Key Laboratory of Advanced Energy Materials Chemistry,Ministry of Education(MOE),Department of Chemistry,Nankai University,Tianjin 300071,China |
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Abstract: | Under solvothermal condition,the reaction of furan-2,5-dicaboxylate(H2FDA) and glycol with Gd(NO3)3.6H2O gave microporous lanthanide metal-organic framework(MOF),{[Gd(FDA)1.5(glycol)].1.5H2O}}n(1).This compound was characterized by single crystal X-ray diffraction,infrared spectroscopy,elemental analysis,thermogravimetry analysis,and powder X-ray diffraction.The Gd(III) ions were connected by carboxylic group of FDA2-to give 1D chains,which were further linked by FDA2-,forming a 3D porous framework with 3D ... |
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Keywords: | crystal structure MOFs channel magnetism gas absorption |
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