| 内嵌富勒烯的研究进展 |
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| 引用本文： | 蒋礼,王太山,舒春英,王春儒.内嵌富勒烯的研究进展[J].中国科学:化学,2011(4):629-644. |
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| 作者姓名： | 蒋礼 王太山 舒春英 王春儒 |
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| 作者单位： | 北京分子科学国家实验室分子纳米结构与纳米技术院重点实验室中国科学院化学研究所; |
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| 基金项目： | 国家自然科学基金青年基金(20903107); 中国博士后科学基金(20100480027)资助 |
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| 摘 要： | 内嵌富勒烯由于其结构新颖以及独特而优异的性质在国际上引起持续而广泛的关注,成为近年来的研究热点之一.目前已经研究发现的内嵌富勒烯多达近百种,从惰性气体到碱土金属再到稀土元素都已被成功地嵌入到不同尺寸的碳笼中.其中金属离子或含金属的离子簇内嵌入富勒烯碳笼形成的内嵌金属富勒烯,以其种类丰富、结构多样成为内嵌富勒烯的主要研究对象.本文就近年来研究报道的种类繁多的内嵌富勒烯按其内嵌物类型进行归纳阐述,为今后开发更多新型的内嵌富勒烯提供一定的参考.
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| 关 键 词： | 内嵌富勒烯 金属化合物团簇 非金属原子内嵌 笼外化学修饰 |
Progress of endohedral fullerenes |
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| JIANG Li,WANG TaiShan,SHU ChunYing & WANG ChunRu Beijing National Laboratory for Molecular Sciences,Key Laboratory of Molecular Nanostructure , Nanotechnology.Progress of endohedral fullerenes[J].Scientia Sinica Chimica,2011(4):629-644. |
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| Authors: | JIANG Li WANG TaiShan SHU ChunYing & WANG ChunRu Beijing National Laboratory for Molecular Sciences Key Laboratory of Molecular Nanostructure Nanotechnology |
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| Institution: | JIANG Li,WANG TaiShan,SHU ChunYing & WANG ChunRu Beijing National Laboratory for Molecular Sciences,Key Laboratory of Molecular Nanostructure and Nanotechnology,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China |
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| Abstract: | Endohedral fullerenes have attracted constantly great interest from all over the world due to not only their novel structure but unique and outstanding properties.So far,hundreds of endohedral fullerenes were reported with different atoms or clusters inside the cage,including inert gases,alkaline earth metal and rare earth metals.The endohedral metal fullerenes,carbon cages embedding metal ions or clusters,are the most interesting subject.In this paper,the latest research progress of endohedral fullerenes a... |
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| Keywords: | endohedral fullerenes metal compound clusters non-metal endohedral chemical modification on carbon cage |
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