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柠檬酸法制备复氧化物材料的配位结构化学
引用本文:陈全亮,陈茂龙,毛少瑜,周朝晖.柠檬酸法制备复氧化物材料的配位结构化学[J].中国科学:化学,2011(4):645-653.
作者姓名:陈全亮  陈茂龙  毛少瑜  周朝晖
作者单位:固体表面物理化学国家重点实验室厦门大学化学化工学院;
基金项目:国家自然科学基金项目(21073150); 国家重点基础研究发展计划(973计划)(2010CB732303)的资助
摘    要:柠檬酸法在复氧化物材料制备中占有重要地位,它具有分散均匀、制备温度低、产物粒径小的特点.以特定组成和结构的柠檬酸络合物为前驱体,直接分解可得到纯度较高的复氧化物,从中可以了解复氧化物的形成过程.本文从配位结构化学的角度,评述以钛、钒、钼和钨柠檬酸络合物为前驱体制备复氧化物材料的研究进展.

关 键 词:柠檬酸  复氧化物  Pechini法  柠檬酸法  

Progress in coordinated structural chemistry to citrate process
CHEN QuanLiang,CHEN MaoLong,MAO ShaoYu & ZHOU ZhaoHui State Key Laboratory of Physical Chemistry of Solid Surfaces,College of Chemistry , Chemical Engineering,Xiamen University,Xiamen ,China.Progress in coordinated structural chemistry to citrate process[J].Scientia Sinica Chimica,2011(4):645-653.
Authors:CHEN QuanLiang  CHEN MaoLong  MAO ShaoYu & ZHOU ZhaoHui State Key Laboratory of Physical Chemistry of Solid Surfaces  College of Chemistry  Chemical Engineering  Xiamen University  Xiamen  China
Institution:CHEN QuanLiang,CHEN MaoLong,MAO ShaoYu & ZHOU ZhaoHui State Key Laboratory of Physical Chemistry of Solid Surfaces,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China
Abstract:Citrate method is one of the popular processes for the synthesis of mixed oxide.This is due to the advantages of its homogeneous,low decomposed temperature,and resulted small particle sizes.Citrate complexes are considered as the molecular precursors for the mixed oxides by thermal decomposition,which may show different compositions and structures.The mixed oxides can be used as catalysts and the other materials by citrate process.In the present paper,recent progress of Ti,V,Mo and W citrate complexes as pr...
Keywords:citric acid  mixed oxides  Pechini method  citrate method  
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