| 功能分子体系的设计与构建 |
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| 引用本文： | 李勇军,李玉良.功能分子体系的设计与构建[J].中国科学:化学,2011(8):1271-1285. |
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| 作者姓名： | 李勇军 李玉良 |
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| 作者单位： | 北京分子科学国家实验室中国科学院化学研究所有机固体院重点实验室; |
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| 基金项目： | 国家自然科学基金(21031006,20831160507,20721061,20971127); 国家重点基础研究发展计划资助 |
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| 摘 要： | 功能分子在外界刺激(酸、碱、光等)的诱导下能发生分子构型、构象变化,并引起相应的物理化学性质变化,或能实现特定的功能,例如具有方向性的电子、能量转移,对分子/离子的识别能力的调控,以及光/电开关功能.功能分子的设计是分子材料科学研究的基础.作者将就我们在分子机器,化学传感器等功能分子的设计合成与性质研究领域取得的进展作一总结,并对未来的发展进行了描述.
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| 关 键 词： | 功能分子 分子机器 化学传感器 |
Design and construction of functional molecular systems |
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| LI YongJun & LI YuLiang Beijing National Laboratory for Molecular Sciences,CAS Key Laboratory of Organic Solids.Design and construction of functional molecular systems[J].Scientia Sinica Chimica,2011(8):1271-1285. |
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| Authors: | LI YongJun & LI YuLiang Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Organic Solids |
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| Institution: | LI YongJun & LI YuLiang Beijing National Laboratory for Molecular Sciences,CAS Key Laboratory of Organic Solids,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China |
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| Abstract: | The conformation and configuration of functional molecules can be changed by the environmental stimulus,and induced some physical or chemical properties changes,or generated some distinct functions,such as directional electron/energy transfer,the tuning of the binding affinity for molecules/ions and photo/electronic switches.The design of functional molecules is the foundation of the molecular materials.Here we summarized our recent progresses on the studies of the design,synthesis and properties of advance... |
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| Keywords: | advanced functional molecular systems molecular machine chemical sensor |
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