A series of 3d-4f heterometallic frameworks comprising 2D lanthanide-organic layers and diverse Cu-complex pillars |
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| Authors: | XU Jing ZHENG ShouTian & YANG GuoYu State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou China |
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| Institution: | XU Jing,ZHENG ShouTian & YANG GuoYu* State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China |
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| Abstract: | Six novel 3D layer-pillared lanthanide-transition metal coordination polymers,LnCuX(IN)2(Ac)(H2O)(Ln = Tb,X = Br(1);Ln = Er,X = Cl(2)),LnCuCl(IN)2(Ac)].H2O(Ln = Gd(3);Ln = Eu(4)),and LnCu2Br2(IN)2(Ac)(H2O)].nH2O(Ln = Dy,n =0(5);Ln = Gd,n = 0.5(6))(IN = isonicotinate,Ac = acetate),have been obtained by linking Ln-organic layers and diverse Cu-complex pillars under hydrothermal conditions.1 and 2 are isostructural and formed by 2D Ln-IN-Ac layers and CuX(IN)2 pillars(X = Br(1),X= Cl(2));3 and 4 are isomorph... |
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| Keywords: | 3d-4f heterometallic frameworks ligands hydrothermal syntheses |
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