| Affiliation: | WANG LiPing1,2,3,4,XIAO Bin1,WANG GongYing1,2* & WU JiQian2 1Chengdu Institute of Organic Chemistry,Chinese Academy of Sciences,Chengdu 610041,China 2Changzhou Key Laboratory of Green and Technology,Changzhou Institute of Chemistry,Changzhou 213164,China 3Graduate School of Chinese Academy of Sciences,Beijing 100039,China 4Department of Chemistry,Qujing Normal College,Qujing 655000,China |
| Abstract: | The metal-organic framework Zn4O[1,4-benzenedicarboxylate]3(Zn4O[CO2-C6H4-CO2]3,commonly known as MOF-5,was prepared by the ultrasonic irradiation method.The catalyst was characterized by X-ray diffraction(XRD) and Fourier transform infrared(FTIR) spectroscopy.It was then used as the catalyst for the preparation of polycarbonate diol(PCDL) via the transesterification between diphenyl carbonate(DPC) and 1,6-hexandiol(1,6-HD).Its catalytic activity in the transesterification process is evaluated by the yield ... |
