Synthesis,structure and photoluminescence of two porous metal-organoboron frameworks with rtl topology |
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| Authors: | LIU Yan XU Xin XUAN WeiMin ZHU ChengFeng & CUI Yong State Key Laboratory of Metal Matrix Composites School of Chemistry Chemical Technology Shanghai Jiao Tong University Shanghai China |
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| Institution: | LIU Yan,XU Xin,XUAN WeiMin,ZHU ChengFeng & CUI Yong* State Key Laboratory of Metal Matrix Composites,School of Chemistry and Chemical Technology,Shanghai Jiao Tong University,Shanghai 200240,China |
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| Abstract: | Rigid trigonal tris(3-pyridylduryl)borane L was synthesized through four steps in good overall yield from readily available 1,2,4,5-tetramethylbenzene and was used to construct two porous cadmium(II) complexes Cd(L)X2.G(X = Cl,Br;G = guset molecules),1(Cd(L)Cl2.EtOH.iPrOH.3H2O) and 2(Cd(L)Br2.MeOH.C7H8.3H2O),under mild reaction conditions.1 and 2 are isostructural and featured with 3D porous metal-organoboron framewoks with rtl topology,in which L acts as a 3-connected node while a dicadmium motif serves as... |
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| Keywords: | boron metal-organic frameworks coordination polymer photoluminescence |
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