| 取代甲基亚磺酰基苯并咪唑类化合物的合成 |
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| 引用本文： | 戴桂元,刘德龙,刘蕴,胡涛,王玉成. 取代甲基亚磺酰基苯并咪唑类化合物的合成[J]. 有机化学, 2003, 23(7): 731-733 |
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| 作者姓名： | 戴桂元 刘德龙 刘蕴 胡涛 王玉成 |
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| 作者单位： | 徐州师范大学化学系,徐州,221116 |
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| 摘 要： | 合成了一系列取代甲基硫代苯并咪唑类化合物，并在过氧乙酸的氧化下得到了 取代甲基亚磺酰基苯并咪唑类化合物，收率较好(79%～97%)，代替了用间氯过氧苯 甲酸进行氧化，反应过程稳定，降低了成本。
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| 关 键 词： | 过氧乙酸 苯并咪唑 P 氧化 亚磺酰基 |
| 修稿时间： | 2002-10-21 |
Syntheses of Substituted 2-Methylsulfinylbenzimidazole Derivatives |
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| DAI,Gui-Yuan LIU,De-long LIU,Yun HU,Tao WANG,Yu-Cheng. Syntheses of Substituted 2-Methylsulfinylbenzimidazole Derivatives[J]. Chinese Journal of Organic Chemistry, 2003, 23(7): 731-733 |
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| Authors: | DAI Gui-Yuan LIU De-long LIU Yun HU Tao WANG Yu-Cheng |
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| Affiliation: | Department of Chemistry, Xuzhou Normal University |
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| Abstract: | A series of substituted 2-methylthiobenzimidazole derivatives were synthesized and then oxidized to give the corresponding sulfoxides in the presence of peracetic acid with excellent yields (79% - 97%) . The process was safe and economic for industry application. |
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| Keywords: | peracetic acid substituted 2-methylsulfinylbenzimidazole oxidation |
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