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Solvatochromic analysis of some N-nitroso oxime derivatives--Taft and Catalan approach
Authors:Jayabharathi Jayaraman  Thanikachalam Venugopal  Padmavathy Manoharan  Perumal Marimuthu Venkatesh
Institution:Department of Chemistry, Annamalai University, Annamalainagar 608002, Tamil Nadu, India. jtchalam2005@yahoo.co.in
Abstract:Some novel N-nitroso oxime derivatives were synthesized and characterized by (1)H, (13)C, (1)H-(1)H and (1)H-(13)C COSY NMR spectra. The spectra of all these N-nitroso oximes reveal the presence of two isomers labelled as E (-NOH group is anti to N-N=O moiety) and Z (-NOH group is syn to N-N=O moiety) in solution and the coupling constants ruled out the possibility of normal chair conformation. From the theoretical studies and coupling constant values it was found that both E (major) and Z (minor) isomers of N-nitroso oximes exist as an equilibrium mixture of CA and boat conformation (B(1)) and this was also supported by DFT calculation. The photophysical properties of these oxime derivatives were studied and the observed lower fluorescence quantum yield may be due to an increase in the non-radiative deactivation rate constant. This is attributed due to the presence of non-chair conformation of N-nitroso oxime derivatives.
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