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Role of triplet states of polymethine dyes in photogeneration of electron-hole pairs in poly(N-epoxypropylcarbazole) films
Authors:N Kh Ibrayev  D A Afanasyev  A A Ishchenko  N A Davidenko
Institution:17377. Institute of Molecular Nanophotonics, Karaganda State University, ul. Universitetskaya 28, Karaganda, 100028, Kazakhstan
27377. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, Kiev, 02094, Ukraine
37377. Kiev National University, ul. Vladimirskaya 60, Kiev, 01601, Ukraine
Abstract:The external magnetic field effects on the spectral and luminescent properties of film composites based on photoconductive poly(N-epoxypropylcarbazole) doped with cationic polymethine and merocyanine dyes have been studied. The magnetic field effects on the intensity and kinetics of delayed fluorescence and recombination luminescence have been revealed. These effects are explained by participation in the photogeneration of charged pairs of singlet-triplet intersystem crossing in excited dye molecules.
Keywords:
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