Extraction of uranium(VI)-pyridylazo dye complexes into a droplet of lipophilic polyoxyethylene nonyl phenyl ether (PONPE-2) for subsequent spectrophotometry |
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Authors: | S Abe M Endo K Ozaki |
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Institution: | (1) Department of Materials Science and Engineering (Applied Chemistry Section), Yamagata University, 992 Yonezawa, Japan |
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Abstract: | Polyoxyethylene nonyl phenyl ether with 2 oxyethylene units (PONPE-2) is immiscible with water and is suspended on the surface of aqueous layer as a droplet. Its unique property is applied to the solvent extraction of uranium(VI) with 5-Br-PADAP. Uranium(VI) chelates are quantitatively enriched into a small volume of PONPE-2 and the absorbance was measured in the mixed ethanol solution. The apparent molar absorptivity of uranium(VI)-5-Br-PADAP complex at 578 nm is 6.46×104 l mol–1 cm–1 and the calibration curve is linear over the range of 0.7–7 g of uranium(VI) per 1.5 ml of the final solution. |
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