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State of components in Pd/C catalysts promoted by Ho2O3
Authors:Yu. A. Ryndin   M. V. Stenin   E. M. Moroz   V. I. Zaikovskii  A. I. Boronin
Affiliation:(1) Institute of Catalysis, 630090 Novosibirsk, USSR
Abstract:Catalysts prepared through the interaction of C3H5PdC5H5 with the surface of evacuated Ho2O3/C after reduction by H2 at 573 K contain Pd and Ho2O3 particles whose size is 30 and 20–40 Å, respectively. XPS and TEM data indicate that Pd particles have a positive charge and their surface is partly covered by Ho oxide.
Kcyacytcyacylcyicyzcyacytcyocyrcyycy, pcyrcyicygcyocytcyocyvcylcyiecyncyncyycyiecy vcyzcyacyicymcyocydcyiecyjcyscytcyvcyicyiecymcy C3H5PdC5H5 scy pcyocyvcyiecyrcykhcyncyocyscytcysoftcyyucy vcyacykcyucyucymcyicyrcyocyvcyacyncyncyocygcyocy Ho2O3/C, pcyocyscylcyiecy vcyocyscyscytcyacyncyocyvcylcyiecyncyicyyacy H2 pcyrcyicy 573 Kcy scyocydcyiecyrcyzhcyacytcy chcyacyscytcyicytscyycy Pd rcyacyzcymcyiecyrcyocymcy 30 Å icy chcyacyscytcyicytscyycy Ho2O3 rcyacyzcymcyiecyrcyocymcy 20–40 Å. Scyocygcylcyacyscyncyocy dcyacyncyncyycymcy XPS icy TEM chcyacyscytcyicytscyycy Pd yacyvcylcyyacyyucytcyscyyacy ecylcyiecykcytcyrcyocypcyocylcyocyzhcyicytcyiecylcysoftcyncyycymcyicy, acy icykhcy pcyocyvcyiecyrcykhcyncyocyscytcysoftcy chcyacyscytcyicychcyncyocy pcyocykcyrcyycytcyacy ocykcyscyicydcyocymcy Ho.
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