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La1—xMxCoO3(M=Ca,Sr)还原性的研究
引用本文:魏诠,崔巍.La1—xMxCoO3(M=Ca,Sr)还原性的研究[J].高等学校化学学报,1990,11(8):855-858.
作者姓名:魏诠  崔巍
作者单位:吉林大学分析测试中心 (魏诠,崔巍),吉林大学分析测试中心(关世权)
摘    要:以XPS和XRD手段研究了La_(1-x)M_xCoO_3复合氧化物的还原性质,得到还原程度次序为La_(1-x)Sr_xCoO_3>La_(1-x)Ca_xCoO_3>LaCoO_3;相同离子取代系列随x增大,还原容易进行,探讨了取代钴酸镧的氢还原机理。

关 键 词:钙钛矿  复合氧化物  还原

Investigation on the Reduction of La_(1-x)M_xCoO_3(M=Ca, Sr) Perovskite Oxides
Wei Quan,Cui Wei,Guan Shiquan.Investigation on the Reduction of La_(1-x)M_xCoO_3(M=Ca, Sr) Perovskite Oxides[J].Chemical Research In Chinese Universities,1990,11(8):855-858.
Authors:Wei Quan  Cui Wei  Guan Shiquan
Abstract:The reduction of La1_xMxCoO3 has been studied by XPS and XRD. The extent of reduction of the perovskite oxides has been obtained as: La1-xSrxCoO3 > La1-xCaxCoO3> LaCoO3; for the same substitution cation, the extent of reduction increases with x. The reduction mechanism of La1-xMxCoO3 was discussed.
Keywords:Perovskite oxides  Reduction  XPS
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