| PtY／Al2O3催化剂活性中心初探 |
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| 引用本文： | 朱光中,石秋杰.PtY／Al2O3催化剂活性中心初探[J].高等学校化学学报,1990,11(11):1301-1303. |
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| 作者姓名： | 朱光中 石秋杰 |
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| 作者单位： | 江西大学化学系 330047
(朱光中，石秋杰)，江西大学化学系 330047(李凤仪) |
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| 摘 要： | 铂铼、铂锡、铂铱等双金属催化剂已有报道,但有关以稀土金属为第2或第3组分的重整催化剂的报道尚很少见,本文报道用中毒法对PtY/Al_2O_3的金属活性中心性质的研究,试图探讨其活性中心与催化性质的某些联系。 1 实验部分 按文献1]制备催化剂,其中Pt、Y、Cl含量分别为0.3、0.1、1.0 wt％,使用前不焙烧,比
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| 关 键 词： | 铂钇催化剂 中毒 活性中心 重整 |
An Investigation in Properties of Active Sites for PtY/Al_2O_3 |
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| Zhu Guangzhong,Shi Qiujie,Li Fengyi.An Investigation in Properties of Active Sites for PtY/Al_2O_3[J].Chemical Research In Chinese Universities,1990,11(11):1301-1303. |
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| Authors: | Zhu Guangzhong Shi Qiujie Li Fengyi |
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| Abstract: | The catalytic reforming and active site properties for Pt/Al2O3 and PtY/Al2O3 were studied by using pulse microcatalytic reactor, TEM and poisoning technnique. The kinetic data of dehydro-genation of c'yclohexane for the two catalysts were calculated. The determination of the total numbers of active sites (TNAS) for the catalysts shows that Y makes TNAS increase. The correlation of the catalytic behavior with the particle size and the properties of active sites for the two catalysts has also been discussed here. |
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| Keywords: | Reforming Yttrium Poisoning of catalyst |
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