| Cr-ZSM-48和V-ZSM-48型分子筛的合成与结构 |
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| 引用本文： | 焦庆祝,庞文琴.Cr-ZSM-48和V-ZSM-48型分子筛的合成与结构[J].高等学校化学学报,1990,11(8):797-799. |
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| 作者姓名： | 焦庆祝 庞文琴 |
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| 作者单位： | 吉林大学合成与催化研究所 |
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| 摘 要： | 合成了新的Cr-ZSM-48型和V-ZSM-48型杂原子分子筛,并进行了结构表征,结果表明,Cr-ZSM-48、V-ZSM-48与全硅ZSM-48结构相同,Cr和V分别以+3和+4价态存在;杂原子以畸变四面体配位方式进入分子筛骨架。
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| 关 键 词： | 铬 钒 ZSM-48型分子筛 合成 结构 |
| 收稿时间： | 1988-11-14 |
Syntheses and Structures of Cr-ZSM-48 and V-ZSM-48 Molecular Sieves |
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| Jiao Qingzhu,Pang Wenqin.Syntheses and Structures of Cr-ZSM-48 and V-ZSM-48 Molecular Sieves[J].Chemical Research In Chinese Universities,1990,11(8):797-799. |
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| Authors: | Jiao Qingzhu Pang Wenqin |
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| Institution: | Institute of Synthetic and Catalytic Chemistry of Jilin University, Changchun |
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| Abstract: | Cr-ZSM-48 and V-ZSM-48 type hetero-atom molecular sieves were synthesized and their structures were characterized by many physicochemical methods. The results show that Cr-ZSM-48, V-ZSM-48 and Silica-ZSM-48 are isostruclural. Cr and V exist as three-valence and four-valence ions respectively. The hetero-atoms are introduced into the framework of the molecular sieves in distortion-al tetrahedral coordination. |
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| Keywords: | Chromium Vanadium ZSM-48 Systhesis Structure |
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