| Theoretical Study on the Pyrolysis Mechanism and Kinetics of 3-Hydroxy-3-Methyl-2-Butanone |
| |
| 引用本文： | Wen Lin FENG, Jie Hao CHEN, Yan WANG (Department of chemistry,Beijing Normal University,Beijing 100875). Theoretical Study on the Pyrolysis Mechanism and Kinetics of 3-Hydroxy-3-Methyl-2-Butanone[J]. 中国化学快报, 1998, 0(11) |
| |
| 作者姓名： | Wen Lin FENG Jie Hao CHEN Yan WANG (Department of chemistry Beijing Normal University Beijing 100875) |
| |
| 作者单位： | Department of chemistry，Beijing Normal University，Beijing 100875 |
| |
| 摘 要： | Thethermolysisofpyruvicacid2Ieadstotheeliminationofcarbondioxideandacetaldehydeisformedasanotherproduct.Hong'hasstudiedthemechanismofthereactionintheMINDO/3molecularorbitaltheory.Al-AwadiandEL-Dusouqui'havestudiedthepyrolysisofthe3-hydroxy-3-methyl-2-butanoneinordertoexaminetheinfluenceofthehydrogenatominvolvedintheTransitionStateoftheeliminationprocessandtoassessitscontributiontotherate-controllingstep.TheygaveoutthethermalrateconstantsandhypothesizedthatthereactionmightproceedthroughafO…
|
Theoretical Study on the Pyrolysis Mechanism and Kinetics of 3-Hydroxy-3-Methyl-2-Butanone |
| |
| Wen Lin FENG, Jie Hao CHEN, Yan WANG. Theoretical Study on the Pyrolysis Mechanism and Kinetics of 3-Hydroxy-3-Methyl-2-Butanone[J]. Chinese Chemical Letters, 1998, 0(11) |
| |
| Authors: | Wen Lin FENG Jie Hao CHEN Yan WANG |
| |
| Abstract: | |
| |
| Keywords: | Kinetics mechanism theoretical study rate constants |
| 本文献已被 CNKI 等数据库收录！ |
