Unexpected transfer of tosyl group of ArCH=NTs-catalyzed by N-heterocyclic carbene |
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| Authors: | Chen Dong-Dong Hou Xue-Long Dai Li-Xin |
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| Affiliation: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China. |
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| Abstract: | ![]()
Reactions of N-tosylimines with aziridines and electron-deficient unsaturated compounds in the presence of catalytic amount of NHC afforded unexpected tosyl group transfer products in good to high yields, which represent a new reaction pattern for imines as well as for catalysis of NHC. |
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