Kinetics of the ionization of monoalkylbenzenes and nitroalkanes in polar solvents. 2. Calculation of the outer-sphere reorganization energy |
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Authors: | É. D. German N. G. Zharova I. O. Shapiro |
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Affiliation: | (1) L. Ya. Karpov Scientific-Research Institute of Physical Chemistry, Moscow;(2) A. N. Frumkin Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions The outer-sphere reorganization energies have been calculated for the ionization of toluene (167 kJ/mole) and cumene (146 kJ/mole) in solutions of potassium tert-butoxide in DMSO.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 326–328, February, 1989. |
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