Stabilization of 1,2-ditellurolane by 2,3,5,6-tetramethylnitrosobenzene (Nitrosodurene) |
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| Authors: | E. P. Levanova T. I. Vakulskaya S. G. Shevchenko V. A. Grabelnykh E. N. Sukhomazova A. I. Albanov N. V. Russavskaya N. A. Korchevin |
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| Affiliation: | (1) A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, 664033, Russia |
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| Abstract: | 1,2-Ditellurolane is an extremely unstable heterocyclic compound which can be maintained in solution in the presence of nitrosodurene for several days. It is proposed on the basis of UV spectroscopy and 1H NMR spectroscopy that a complex is formed which determines the stability of 1,2-ditellurolane. It is shown that stabilized 1,2-ditellurolane can be used in organic synthesis. Presented to Academician of the Russian Academy of Sciences Boris Aleksandrovich Trofimov on his 70th jubilee. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, 1736–1738, November, 2008. |
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| Keywords: | 1,2-ditellurolane nitrosodurene complex with charge transfer |
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