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Mechanisms of surface diffusion
Authors:Tien T Tsong
Institution:

Institute of Physics, Academia Sinica, Taipei 11529, Taiwan, ROC

Abstract:Mechanisms of surface diffusion of single atoms, molecules and atomic clusters on flat terraces (with and without a driving force) of metal and semiconductor surfaces are discussed, focusing on our recent scanning tunneling microscopy (STM) results. Experimental evidence leading to these conclusions is presented. Besides the commonly known hopping mechanism, there are many other mechanisms. In Arrhenius analysis, a linear behavior can be expected for only some of the simpler mechanisms.
Keywords:Diffusion  Surface diffusion  Hopping mechanism  Tunneling mechanism  Atomic-exchange mechanism  Tumbling mechanism  Bond stretching mechanism  Periphery diffusion mechanism  Evaporation condensation mechanism  Gliding mechanism  Glide and lock-in mechanism
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