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Aerobic oxidation of benzylic aldehydes to acids catalyzed by iron (Ⅲ) meso-tetraphenylporphyrin chloride under ambient conditions
作者姓名:Xian  Tai  Zhou  Hong  Bing  Ji  Qiu  Lan  Yuan  Jian  Chang  Xu  Li  Xia  Pei  Le  Fu  Wang
作者单位:Xian Tai Zhou Hong Bing Ji~* Qiu Lan Yuan Jian Chang Xu Li Xia Pei Le Fu Wang School of Chemical and Energy Engineering,South China University of Technology,Guangzhou 510640,China
基金项目:The authors thank the National Natural Science Foundation of China (No. 20576045) and the Program for New Century Excellent Talents in University (NCET) for the financial support.
摘    要:Highly efficient aerobic oxidation of benzylic aldehydes to the corresponding acids catalyzed by iron (Ⅲ) meso-tetraphe- nylporphyrin chloride (Fe(TPP)Cl) under ambient conditions was developed.The catalyst has been proved to be an excellent catalyst for the system in the presence of molecular oxygen and isobutryaldehyde at room temperature.

关 键 词:苄型乙醛  氧化  金属卟啉  催化合成
收稿时间:21 January 2007
修稿时间:2007-01-21

Aerobic oxidation of benzylic aldehydes to acids catalyzed by iron (III) meso-tetraphenylporphyrin chloride under ambient conditions
Xian Tai Zhou Hong Bing Ji Qiu Lan Yuan Jian Chang Xu Li Xia Pei Le Fu Wang.Aerobic oxidation of benzylic aldehydes to acids catalyzed by iron (III) meso-tetraphenylporphyrin chloride under ambient conditions[J].Chinese Chemical Letters,2007,18(8):926-928.
Authors:Xian Tai Zhou  Hong Bing Ji  Qiu Lan Yuan  Jian Chang Xu  Li Xia Pei  Le Fu Wang  
Institution:School of Chemical and Energy Engineering, South China University of Technology, Guangzhou 510640, China
Abstract:Highly efficient aerobic oxidation of benzylic aldehydes to the corresponding acids catalyzed by iron (III) meso-tetraphenylporphyrin chloride (Fe(TPP)Cl) under ambient conditions was developed. The catalyst has been proved to be an excellent catalyst for the system in the presence of molecular oxygen and isobutryaldehyde at room temperature.
Keywords:Benzylic aldehydes  Oxidation  Metalloporphyrins
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