Chiral benzyl centers through asymmetric catalysis. a three-step synthesis of (R)-(-)-alpha-curcumene via asymmetric hydrovinylation |
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| Authors: | Zhang Aibin RajanBabu T V |
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| Institution: | Department of Chemistry, 100 West 18th Avenue, The Ohio State University, Columbus, Ohio 43210, USA. |
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| Abstract: | reaction: see text] A three-step, two-pot procedure involving asymmetric hydrovinylation followed by Suzuki-Miyaura reaction represents by far the shortest synthesis of this popular bisabolane. Other applications for the synthesis of similar compounds with chiral benzyl centers can be easily envisioned. |
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