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Anion recognition by a disiloxane-1,3-diol in organic solvents
Authors:Shin-ichi Kondo  Ayumi Fukuda
Affiliation:Department of Chemistry and Chemical Biology, Graduate School of Engineering, Gunma University, Kiryu, Gunma 376-8515, Japan
Abstract:To explore the anion recognition ability of silanol derivatives, ESI-MS and 1H NMR titrations of a 1,3-disiloxanediol 1 with anions were studied in CDCl3 and MeCN-d3. The results indicate that 1 showed strong binding to anions such as AcO and halides.
Keywords:Anion recognition   Silanol   1,3-Disiloxanediol   Hydrogen bond
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