Cationic copolymerization of tetrahydrofuran with ethylene oxide in the presence of diols: Composition,microstructure, and properties of copolymers |
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Authors: | Melania Bednarek Przemyslaw Kubisa |
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Affiliation: | Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-362 Lodz, Poland |
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Abstract: | Cationic copolymerization of tetrahydrofuran (THF) with ethylene oxide (EO) in the presence of diols leads to dihydroxy terminated telechelic copolymers. In the present article the influence of copolymerization conditions on the copolymer structure was studied in view of conclusions derived from studies of copolymerization kinetics and mechanism. It was shown that according to established copolymerization mechanism, the number average molecular weights increase linearly with conversion up to Mn ≅ 2500, hydroxyl end groups are bound exclusively to EO units and copolymers are composed of [EO]–[THF]y segments. Microstructure of copolymers may be to some extent regulated by changing reaction conditions. Some physical properties of copolymers also were studied. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 3455–3463, 1999 |
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Keywords: | telechelic copolyethers cationic copolymerization tetrahydrofuran ehtylene oxide microstructure of copolyethers |
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