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Bulk polymerization of N-vinylcarbazole initiated by C60 |
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| Authors: | Yu Chen Jingxia Wang Jianzhong Shen Ruifang Cai Zuen Huang |
| Abstract: | In this communication, we first used 60]fullerene as initiator to initiate the bulk polymerization of N-vinylcarbazole (NVC) monomer at 70°C (slightly higher than the melting point temperature, 65°C, of NVC). A reasonable polymerization reaction pathway via C60-NVC ion-radical pairs is suggested. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 3745–3747, 1999 |
| Keywords: | bulk polymerization [60]fullerene N-vinylcarbazole charge transfer initiator |