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On the versatility of fluorescence techniques in polymer research
Authors:Herbert Morawetz
Abstract:Examples are given for the application of fluorescence to the study of the following polymer problems: (a) the excluded volume effect as reflected in the kinetics of interpolymer reactions; (b) evidence for the microheterogeneity of polymer solutions; (c) kinetics of conformational transitions of polymer chain backbones. (d) Interpenetration of polymer chains; (e) the structure and molecular association of polymers in water solution; (f) ionomer behavior; (g) the “antenna effect.” © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 1725–1735, 1999
Keywords:fluorescence  energy transfer  excimers  interpolymer reactions  excluded volume  polyelectrolytes  polyelectrolyte association  counterion interchange  counterion condensation  conformational mobility  polymer compatibility  polymer association  ion pairs  poly(methacrylic acid)  block polymers  hydrophobic effect  photon harvesting
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