Synthese,Struktur und Charakterisierung von Titan‐, Zink‐, Nickel‐ und Palladium‐Thioether‐Thiolat‐Komplexen heterocyclischer 1,2‐Dithiolate

Synthesis, Structures, and Characterization of Titanium, Zinc, Nickel, and Palladium Thioether Thiolate Complexes of Heterocyclic 1,2‐Dithiolates Synthesis and properties of mixed ligand complexes of thioether thiolate ligands 4‐methylthio‐1,3‐dithiole‐2‐one‐5‐thiolate (dmidCH₃), 4‐methylthio‐1,3‐dithiole‐2‐thione‐5‐thiolate (dmitCH₃), and 4‐methylthio‐1,3‐dithiole‐2‐selone‐5‐thiolate (dmiseCH₃) are described. The x‐ray structures of CpTi(dmidCH₃)₂ (Cp′ = methylcyclopentadienyl), of two polymorphic structures of (tmeda)Zn(dmitCH₃)₂ tmeda = 1,2‐bis(dimethylamino)ethane], of (dppe)Ni(dmitCH₃)₂, and (dppe)Pd(dmitCH₃)₂ dppe=1,2‐bis(diphenylphosphino)ethane] are reported.