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A Functionalized Heterocubane with Extensive Intermolecular Hydrogen Bonds |
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| Authors: | Musa A Said Herbert W Roesky Carsten Rennekamp Marius Andruh Hans‐Georg Schmidt Mathias Noltemeyer |
| Abstract: | A unique three‐dimensional assembly is evident in the crystal structure of the cage compound 1 : each molecule participates in the formation of eight O?H???O hydrogen bonds with neighboring molecules to form cavities with approximate dimensions of 3×3×8 Å3. In contrast, compound 2 , which contains the same framework structure, does not show this behavior in the crystal. |
| Keywords: | Cage compounds Hydrogen bonds Silicon |