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Enantioselective Inclusion Complexation of N‐Nitrosopiperidines by Steroidal Bile Acids
Authors:Maria Gdaniec  Maria J Milewska  Tadeusz Po&#x;o&#x;ski
Abstract:N ‐nitrosamines , whose chirality is solely due to hindered rotation about the N−N bond, are enantioselectively enclathrated by the crystal host matrices of cholic or deoxycholic acid, as evidenced by X‐ray crystallography (see structure in picture) and CD spectra.
Keywords:Chirality  Circular dichroism  Inclusion compounds  Solid‐state structures
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