|
|||||
|
|
Hydrogen‐Bonding Cavities about Metal Ions: A Redox Pair of Coordinatively Unsaturated Paramagnetic Co–OH Complexes |
|
| Authors: | Brian S. Hammes Victor G. Young Jr. Andrew S. Borovik |
| Abstract: | Nature uses hydrogen bonds to regulate a variety of metal‐based reactions. These effects are emulated in the stabilization of trigonal‐bipyramidal, paramagnetic Co–OH complexes such as the mono‐ or dianionic redox‐active complex 1 by use of a new hydrogen‐bonding ligand. |
| Keywords: | Cobalt Hydrogen bonds Hydroxo ligands Ligand effects |