Synthesis,Structure, and Redox Properties of [{(η5-C5H5)Co(S2C6H4)}2Mo(CO)2], a Novel Metalladithiolene Cluster |
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| Authors: | Masayuki Nihei Takuya Nankawa Masato Kurihara Hiroshi Nishihara |
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| Abstract: | Metal–metal bond formation by a cobaltadithiolene complex was observed for the first time in the reaction of Co(η5-C5H5)(S2C6H4)] with Mo(CO)3(py)3] and BF3 to give the Co-Mo-Co cluster 1 . Cyclic voltammetry reveals that 1 undergoes two one-electron reduction steps at the Co centers, which is indicative of transmission of the Co−Co electronic interaction through the Mo center. |
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| Keywords: | Cobalt Cyclic voltammetry Mixed-valent compounds Molybdenum S ligands |
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