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Surface-Confined Metallodendrimers: Isolated Nanosize Molecules |
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| Authors: | Bart-Hendrik Huisman,Holger Schö nherr,Wilhelm T. S. Huck,Arianna Friggeri,Henk-Jan van Manen,Edoardo Menozzi,G. Julius Vancso,Frank C. J. M. van Veggel,David N. Reinhoudt |
| Abstract: | The incorporation of dialkyl sulfide side chains in metallodendrimers is a simple method for their insertion into a monolayer of decanethiol formed by self-assembly on a gold surface. The dendrimer binds through the sulfide group to a defect in the monolayer on the gold surface (see picture). The surface concentration of the isolated dendrimer adsorbate can be regulated by the adsorption time (for example, 55 adsorbates on a surface of 200×200 nm2 after 20 h). |
| Keywords: | Atomic force microscopy Dendrimers Monolayers Nanostructures Surface chemistry |