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Synthesis and Structure of [NbCl3(NPPh2Fc)2]: The First Example of a Complex Containing a Redox‐functionalised Phosphaneiminato Ligand |
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| Authors: | Ulrich Siemeling Anja Stammler Hans‐Georg Stammler Oliver Kuhnert |
| Abstract: | Reaction of Me3SiNPPh2Fc (Fc = ferrocenyl) with niobium pentachloride affords NbCl3(NPPh2Fc)2], whose redox‐functionalised phosphaneiminato ligands exhibit remarkably different bend angles at nitrogen according to a crystal structure analysis. |
| Keywords: | Crystal Structure Ferrocene Iron Niobium Phosphaneiminato Complex |