| Abstract: | New Organometallic Indium Nitrogen Compounds. Synthesis and Crystal Structures of {Cp(CO)3Mo}2InN(SiMe3)2] and {Cp(CO)3Mo}In{N(SiMe3)2}2] The reaction of {Cp(CO)3Mo}2InCl] with LiN · (SiMe3)2 leads to the formation of {Cp(CO)3Mo}2InN · (SiMe3)2] ( 1 ). 1 is monomeric and it contains an indium atom which is coordinated in a trigonal planar manner by two {Cp(CO)3Mo} fragments and a N(SiMe3)2 group. The corresponding bis-amide {Cp(CO)3Mo}In{N(SiMe3)2}2] ( 2 ) is prepared by the reaction of {Cp(CO)3Mo}InCl2] with two equivalents of LiN(SiMe3)2. In analogy to 1, 2 is monomeric and it contains an indium atom in a trigonal planar coordination. |
