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[{MeAl(μ2-F)}2N(2,6-iPr2C6H3)]4— A Molecular Al-F-N Cage Compound
Authors:Helge Wessel,Hyung-Suh Park,Peter Mü  ller,Herbert W. Roesky,Isabel Usó  n
Abstract:In a two-step elimination reaction the molecular Al-F-N cage compound 1 is synthesized from (2,6-iPr2C6H3)NH2 (ArNH2) and Me2AlF under methane evolution. Compound 1 was characterized by means of X-ray structure analysis and can be regarded as a precursor for ternary Al-F-N systems.
Keywords:Aluminum  Aminoalanes  Cage compounds  Fluorine
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