Bildung eines 14-gliedrigen (SiNC4O)2-Heterocyclus – THF-Spaltung und Addition an die Si–N-Bindung |
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| Authors: | Bettina Jaschke Regine Herbst-Irmer Uwe Klingebiel Peter Neugebauer Thomas Pape |
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| Abstract: | Formation of a 14-Membered (SiNC4O)2 Heterocyclus – THF-Cleavage and Addition on the Si–N Bond Lithiated di-tert.-butylmethylsilylaminotrichlorosilane reacts with tetrahydrofurane with formation of the 14-membered heterocyclus 1 (CMe3)2MeSi–N–SiCl2–O(CH2)4]2 and LiCl. The mechanism of the THF-cleavage is discussed and the results of the crystal structure of 1 are reported. |
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| Keywords: | Silicon Macrocycle THF-Cleavage Crystal Structure |
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