Darstellung,Kristallstruktur und IR‐Spektren von BeSeO3 · H2O – Wasserstoffbrücken und Korrelation von IR‐ und Strukturdaten in den Monohydraten MSeO3 · H2O (M = Be,Ca, Mn,Co, Ni,Zn, Cd) |
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Authors: | U Bumer K Boldt B Engelen H Müller K Unterderweide |
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Abstract: | Preparation, Crystal Structure and IR Spectra of BeSeO3 · H2O – Hydrogen Bonds and Correlation of IR and Structure Data in the Monohydrates MSeO3 · H2O (M = Be, Ca, Mn, Co, Ni, Zn, Cd) BeSeO3 · H2O (oP32) has been obtained by treating amorphous BeSeO3 · 4 H2O precipitated from Be(HSeO3)2 solutions hydrothermally at 150 °C. The crystal structure (P212121, a = 560.59(4), b = 755.25(5), c = 781.14(5) pm, Z = 4, DX = 3.092 gcm–3, R = 0.018 for the 2034 reflections with I > 2σI of the enantiomer investigated) contains BeO3(H2O) tetrahedra built up from three selenite and one water oxygen atoms. The BeO3(H2O) tetrahedra are 3 D‐connected via Se atoms of trigonal pyramidal SeO32– ions. The Be–O distances are 161.8 to 164.4 pm. The Se–O bond lenghts (169.2–170.3 pm) and the O–Se–O bond angles (98.1–101.4°) are normal. The water molecules of crystallization form together with the SeO32– ions screw‐like hydrogen bond systems along 100]. Despite the strong synergetic effect of the Be2+ ions, the hydrogen bonds (d(OH…O) = 267.4 and 276.4 pm, respectively; νOD of matrix isolated HDO molecules: 2244 and 2405 cm–1, respectively) are normal compared to other neutral selenite hydrates. Together with the hitherto known monohydrates MIISeO3 · H2O and other beryllium salt hydrates, the hydrogen bonds of BeSeO3 · H2O are discussed with regard to their geometry and IR spectroscopy. |
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Keywords: | Beryllium Selenites Hydrates Hydrogen Bonds Crystal Structure X‐ray Vibrational spectra |
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