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Compatibilized poly(ϵ‐caprolactone)/poly(L‐lactide) blends for biomedical uses
Authors:Giovanni Maglio  Anna Migliozzi  Rosario Palumbo  Barbara Immirzi  Maria Grazia Volpe
Abstract:A binary poly(L ‐lactide)/poly(ε‐caprolactone) (PLLA/PCL) (70/30 w/w) blend and a ternary PLLA/PCL/PLLA‐PCL‐PLLA blend of the same composition which contains 4 wt.‐% of a triblock PLLA‐PCL‐PLLA copolyester as compatibilizing agent were prepared by melt mixing at 200°C. Investigation of the thermal and mechanical properties of the blends and scanning electron microscopy of their fracture surfaces showed in the case of the ternary blend a better state of dispersion of PCL in the PLLA matrix and an improved toughness.
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