Infrared and Raman spectral interpretations of the ferroelectric phases of NaH3(SeO3)2 and NaD3(SeO3)2期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

按检索

Infrared and Raman spectral interpretations of the ferroelectric phases of NaH3(SeO3)2 and NaD3(SeO3)2

Authors:	CA Cody RC Levitt RK Khanna Philip J Miller

Institution:	Chemistry Department, University of Maryland, College Park, Maryland 20742 USA;Department of Chemistry, University of Detroit, Detroit, Michigan 48221 USA

Abstract:	The infrared and Raman spectra of NaH₃(SeO₃)₂ and NaD₃(SeO₃)₂ have been recorded from 24 to 300°K. The interpretation, assignments, and analysis of the spectral studies are presented on the paraelectric α phase (proton disordered), ferroelectric β phase (proton ordered) and ferroelectric γ phase (proton ordered). A discussion of a newly proposed proton-triggered phase transition mechanism and a possible origin of the hydrogen-bonded OH stretching region of KH₂PO₄-type ferroelectrics is given.

Keywords:
本文献已被 ScienceDirect 等数据库收录！