Phosphides with Zr2Fe12P7-type structure |
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| Authors: | W Jeitschko DJ Braun RH Ashcraft R Marchand |
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| Institution: | Institut für Anorganische und Analytische Chemie, Universität Giessen, D-6300 Giessen, West Germany |
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| Abstract: | Twenty-six ternary phosphides Ln2T12P7 (Ln = lanthanoid, T = Fe, Co, Ni) were prepared for the first time by reaction of the elemental components in liquid tin or by reaction of the components in evacuated silica tubes. The analysis of their powder patterns indicates their isotypism with Zr2Fe12P7. Their lattice constants are reported. Gd2Ni12As7 also crystallizes with that structure. |
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