Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XLI. Solvent Effect on the Rate of 3-Methyl-3-chloro-1-butene Solvolysis. Correlation Analysis of Solvation Effects and Role of Solvent Nucleophilicity |
| |
| Authors: | N E Ponomarev V V Zaliznyi G F Dvorko |
| |
| Institution: | (1) Kiev Polytechnic Institute, National Technical University of Ukraine, Kiev, Ukraine |
| |
| Abstract: | The kinetics of 3-methyl-3-chloro-1-butene solvolysis at 25°C in MeOH, EtOH, BuOH, i-BuOH, PentOH, 2-PrOH, 2-BuOH, HexOH, OctOH, t-BuOH, t-PentOH, cyclohexanol, and allyl alcohol was studied by the verdazyl method; v = kC5H9Cl], SN1 + E1 mechanism. The reaction rate shows a satisfactory correlation with the parameter of the solvent ionizing power E T and is independent of the solvent nucleophilicity. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
