Real-time probing of vectorial properties of ultra-fast photodissociations in liquids |
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| Authors: | H Bürsing J Lindner S Hess P Vöhringer |
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| Institution: | Max-Planck-Institute for Biophysical Chemistry, Biomolecular and Chemical, Dynamics Group, Am Fassberg 11, 37077 G?ttingen, Germany (Fax: +49-551/201-1341, E-mail: pvoehri@gwdg.de), DE
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| Abstract: | Polarization-resolved femtosecond experiments are shown to yield valuable insight into transition-state dynamics associated
with ultra-fast photodissociation reactions of triatomic species in liquid solution. After the fundamental act of bond fission
is completed, such experiments reveal rotational dynamics of the fragments, which can be used to extract information regarding
fragment rotational excitation in the asymptotic limit of the reaction.
Received: 4 October 1999 / Published online: 30 June 2000 |
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| Keywords: | PACS: 78 47+p 82 40 Js 82 50 Fv |
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