| Helix—Sense—Selective Polymerization of N,N—Diphenyl （Meth） acrylamide by Anionic Catalysts |
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| 引用本文： | HongXUE YongAnXU 等.Helix—Sense—Selective Polymerization of N,N—Diphenyl （Meth） acrylamide by Anionic Catalysts[J].中国化学快报,2002,13(7):678-680. |
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| 作者姓名： | HongXUE YongAnXU |
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| 作者单位： | [1]StateKeyLaboratoryofPolymerPhysicsandChemistry,ChangchunInstituteofAppliedChemistry,ChineseAcademyofSciences,Changchun130022 [2]StateKeyLaboratoryofPolymerPhysicsandChemistry,ChangchunInstituteofAppliedC |
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| 基金项目： | The authors are grateful to the National Natural Science Foundation of China for financial support. |
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| 摘 要： | In this paper, the helix-sense-selective polymerization of N,N-diphenyl acrylamide (DPAA) and N,N-diphenyl methacrylamide (DPMAA) were studied with living helix prepolymer as anionic initiator, and the chiral optical properties of the obtained polymers were investigated too. It was shown that optically active polymers of DPAA and DPMAA could be obtained under the experimental condition, and exhibited the same screw sense as that of the prepolymer.
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| 关 键 词： | 阴离子催化剂 N，N－二苯基丙烯酰胺 螺旋聚合反应 |
Helix-Sense-Selective Polymerization of N,N-Diphenyl(Meth)acrylamide by Anionic Catalysts |
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| Hong XUE,Yong An XU,Bin YU,Lian Xun GAO,Meng Xian DING.Helix-Sense-Selective Polymerization of N,N-Diphenyl(Meth)acrylamide by Anionic Catalysts[J].Chinese Chemical Letters,2002,13(7):678-680. |
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| Authors: | Hong XUE Yong An XU Bin YU Lian Xun GAO Meng Xian DING |
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| Abstract: | In this paper, the helix-sense-selective polymerization of N,N-diphenyl acrylamide (DPAA) and N,N-diphenyl methacrylamide(DPMAA) were studied with living helix prepolymer as anionic initiator, and the chiral optical properties of the obtained polymers were investigated too. It was shown that optically active polymers of DPAA and DPMAA could be obtained under the experimental condition, and exhibited the same screw sense as that of the prepolymer. |
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| Keywords: | Helix-sense-selective polymerization N N-diphenyl (meth)acrylamide specific rota- tion |
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